Interakce anorganických klastrových sloučenin se světlem

The Effect of Iodination on the Photophysics of the Laser Borane anti B 18 H 22 The Generation of Efficient Photosensitizers of Oxygen

Institute of Inorganic Chemistry

Anaddition to our growing portfolio of usefullyluminescent boranes from the working groupInteractions of Inorganic Clusters Cages andContainers with Light within the AV 21 StrategyCzech Academy of Sciences Iodination of laserborane anti B 18 H 22 gives strongly phosphorescentderivatives, B 18 H 21 I and B 18 H 20 I 2 that are capable ofhigh quantum yield singlet oxygen production withthe option of two photon excitation at wavelengthswhich fall within the biological therapeutic window,making the pair of compounds promising O 21 Δ gphoto sensitizers

Michael G. S. Londesborough *, Jiří Dolanský , Jonathan Bould , Jakub Braborec , Kaplan Kirakci Kamil Lang, Ivana
Císařová , Pavel Kubát , Daniel Roca Sanjuán , Antonio Francés Monerris , Lenka Slušná , Eva Noskovičová , Dušan Lorenc , Inorg . 2019 , 58 , 15 , 10248 10259