Interakce anorganických klastrových sloučenin se světlem

A Reversible NO Triggered Multiple Metallaborane Cluster Fusion by Ligand Expulsion/Addition

Institute of Inorganic Chemistry

A Reversible NO Triggered Multiple Metallaborane Cluster Fusion by Ligand Expulsion/Addition from (PMe 2 Ph) 4 Pt 2 B 10 H 10 to Afford (PMe 2 Ph) 8 Pt 8 B 40 H 40 and (PMe 2 Ph) 5 Pt 4 B 20 H 20

Lighting up the night sky, our new octaplatinaborane {Pt 8 B 40 cluster A further contribution from the working group Interactions of Inorganic Clusters, Cages, and Containers with Light within the AV 21 Strategy, Czech Academy of Sciences The eight platinum atoms self organise into a geometry similar to the Hercules Constellation Simply stellar chemistry! These metallaborane assemblies show interesting interaction with small molecules, such as nitric oxide a biologically important species

Jonathan Bould **, William Clegg Paul Waddell, Josef Cva čka, Michal Dušek and Michael G. S. Londesborough Inorg . Chem 2020 , 59 , 7 , 5030 5040